Tiny devices called microelectronics may one day be printed as easily as words on a page, thanks to new research.
Building on years of progress in printed electronics, a team from Argonne National Laboratory and the University of Chicago has shown a new way to create durable, low-power electronic switches, called transistors. This research could help create flexible sensors, smart windows and other new technologies that need reliable, energy-saving electronics.
“We chose printing methods for two main reasons,” said Argonne materials scientist Yuepeng Zhang. “First, printing enables rapid prototyping and iterative design, which helps us optimize materials and device structures quickly. Second, printed electronics have benefits for device functionality, especially since our devices show a well-modulated current response to voltage, making them suitable for printed logic devices and niche applications.”
The scientists used a method called aerosol jet printing, which works like an inkjet printer but uses specially formulated ink made from nanoparticles. The printer turns the ink into a fine mist and sprays it onto a surface, building up layers to form electronic parts.
Unlike traditional manufacturing, which often requires expensive equipment and high temperatures, aerosol jet printing works at lower temperatures and can print on flexible or even 3D surfaces. This approach makes it easier and faster to develop and test new electronic designs.
To fine-tune these inks, the team used the Center for Nanoscale Materials at Argonne, to watch how nanoparticles clump together, see how they change with heat and check the stability and makeup of the dried films—insights that helped improve the ink formulations.
They also used X-ray tools at Argonne’s Advanced Photon Source to map the shape and elemental makeup of the printed devices, complementing studies at Brookhaven National Laboratory in New York. All of these are user facilities from the Department of Energy (DOE) Office of Science.
A key ingredient in these printed devices is vanadium dioxide. This material is special because it can act like a wire, letting electricity flow, or like an insulator, blocking electricity. This switching ability is important for making electronic circuits and memory devices, which store and process information.
By using these properties, the printed transistors use very little power, are built to last and show new behaviors not seen in earlier printed devices. To control the flow of electricity, the team used a process called redox gating. In simple terms, this means they use a chemical reaction to add or remove electrons from the vanadium dioxide.
By applying a small voltage—less than what is used in a typical battery—they can turn the transistor on or off. This method is less harsh than other techniques, which could damage the material and make devices wear out quickly.
UChicago CASE scientist Wei Chen emphasized the durability of the new devices.
“Redox gating is robust and does not damage the materials, so we can run thousands of cycles without issues,” he said. “In previous methods, devices could only run a few times, sometimes just 10 cycles, before failing. Our devices can run thousands of cycles with no problem.”
In laboratory tests, the printed transistors operated at voltages as low as 0.4 to 0.5 volts and kept working for more than 6,000 on-off cycles, which is much longer than previous printed devices. The switches also responded quickly, changing states in about one second.
When the printed transistor was switched on using a small control signal of 0.5 volts, it allowed about 50% more electricity to flow through it compared to when it was off. In other words, the device could boost the flow of electric current by half with just a tiny amount of power. This shows that the transistor can reliably control electricity using very little energy, which is important for making low-power and flexible electronic devices.
Right now, these printed transistors are larger and slower than the tiny silicon chips found in most electronics. But this research shows that it is possible to make strong, low-power devices with printing methods.
Chen added that the lab is already in contact with industry partners interested in testing the process for logic devices, the basic building blocks for computers. The researchers are also exploring how these printed devices could be used in neuromorphic computing, an area that mimics the way the human brain processes information.
To move printed electronics from the lab to real products, the researchers say more teamwork is needed between scientists and industry. They also believe that artificial intelligence and machine learning could help improve the printing process and make development faster.
“Printing involves many variables to adjust, and machine learning can help us find the best settings more quickly,” Zhang said.
With more research and collaboration, printed hybrid electronics could help make future technology more flexible, affordable and energy efficient.
The results of this research were published in Advanced Materials Technology.
Other contributors to this work include Samuel Miller and Hua Zhou from Argonne; and Evan Musterman, Andrew Kiss and Yang Yang from the National Synchrotron Light Source II at DOE’s Brookhaven National Laboratory. Andrew Erwin and Shiyu Hu were at Argonne when this research was conducted.
This work was primarily supported by the Laboratory Directed Research and Development program at Argonne, with additional support from DOE’s Office of Science, Basic Energy Sciences.
—Adapted from an article originally published on the Argonne website.
